Phosphates & Corrosion Inhibitors

MBT (2-Mercaptobenzothiazole)

CAS 149-30-4 — Copper & Yellow Metal Corrosion Inhibitor

MBT is the industry-standard copper and yellow metal corrosion inhibitor for metalworking fluids, cooling water systems, and antifreeze formulations. Texas-Chem supplies industrial-grade MBT in bulk drums and totes.

CAS Number

149-30-4

Formula

C₇H₅NS₂

Melting Point

177–181 °C

Pack Sizes

Drums · Totes

Structure

C₇H₅NS₂ — 2-MercaptobenzothiazoleBenzothiazole+ SH groupCopper passivatorCAS 149-30-4 | Cu/brass/bronze protection

C₇H₅NS₂ — 2-Mercaptobenzothiazole — CAS 149-30-4

Safety & Regulatory

NFPA Health
2 — Moderate hazard
NFPA Flammability
1 — Slight hazard
NFPA Reactivity
0 — Stable
OSHA PEL
Consult SDS for specific components
DOT Hazard Class
Not regulated
Skin Sensitizer
Yes — wear gloves and eye protection

Grades & Packaging

Available Grades

IndustrialTechnical

Pack Sizes

55-gal Drums275-gal Totes

Also Known As

2-MercaptobenzothiazoleMBTCaptaxBenzothiazole-2-thiol

Physical & Chemical Properties

CAS Number149-30-4
Molecular FormulaC₇H₅NS₂
Molecular Weight167.25 g/mol
AppearanceLight yellow to tan powder or flakes
Melting Point177–181 °C
Solubility in Water0.3 g/L at 25 °C (slightly soluble)
Solubility in AlkaliSoluble as sodium salt (NaMBT)
Flash PointAbove 200 °C
Density1.42 g/cm³
Purity98% minimum
Copper InhibitionExcellent — forms protective Cu-MBT film
Biocide ActivityModerate — fungistatic

Industrial Applications

Metalworking Fluids

MBT is used as a copper and yellow metal corrosion inhibitor in metalworking fluids, cutting oils, and grinding fluids to protect brass, bronze, and copper components in machine tools and workpieces.

Cooling Water Treatment

Used as a copper corrosion inhibitor in cooling water systems, forming a protective Cu-MBT film on copper heat exchanger tubes and piping. Effective at 1–5 ppm treat rate.

Antifreeze & Engine Coolants

MBT is used as a copper corrosion inhibitor in engine coolant formulations to protect copper and brass radiator components in automotive and heavy-duty diesel engines.

Rubber Vulcanization

MBT is used as an accelerator in rubber vulcanization, improving the rate and efficiency of sulfur crosslinking in natural and synthetic rubber compounds.

Biocide Applications

MBT has fungistatic activity and is used as a preservative in metalworking fluids, latex paints, and industrial water systems to control fungal growth.

Hydraulic Fluids

Used as a copper corrosion inhibitor in water-glycol hydraulic fluids and other water-based hydraulic fluid formulations.

Why Source MBT from Texas-Chem

  • Industrial-grade MBT in stock — drums and totes
  • Consistent quality with CoA on every lot
  • Same-week delivery across Texas; nationwide LTL
  • Technical support for metalworking fluid and cooling water applications
  • One rep from first call to final delivery
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MBT — Frequently Asked Questions

What is the difference between MBT and benzotriazole (BTA) as copper inhibitors?▾

Both MBT and BTA form protective films on copper surfaces, but through different mechanisms. BTA forms a polymeric Cu-BTA complex that provides excellent protection at very low concentrations (1–5 ppm). MBT forms a Cu-MBT film and also provides some biocide activity. BTA is generally preferred for copper protection in cooling water and antifreeze; MBT is preferred when biocide activity is also needed. Contact Texas-Chem at 855-TEX-CHEM for application guidance.

How is MBT dissolved for use in water-based systems?▾

MBT is slightly soluble in water (0.3 g/L) but dissolves readily as the sodium salt (NaMBT) in alkaline solutions. To prepare a working solution, dissolve MBT in dilute sodium hydroxide solution (pH 9–10) to form NaMBT, then add to the water-based system. Alternatively, use pre-dissolved NaMBT liquid concentrate. Contact Texas-Chem for NaMBT availability.

What is the typical treat rate for MBT in metalworking fluids?▾

MBT is typically used at 0.05–0.5% by weight in metalworking fluid concentrates, which dilutes to 5–50 ppm in the working emulsion. The treat rate depends on the copper content of the machine tool components and the severity of the machining operation. Contact Texas-Chem at 855-TEX-CHEM for formulation guidance.

Is MBT compatible with all metalworking fluid types?▾

MBT is compatible with soluble oil (emulsifiable oil), semi-synthetic, and synthetic metalworking fluid types. It is not compatible with strong oxidizing agents or strong acids. In alkaline metalworking fluids (pH 8.5–9.5), MBT provides excellent copper protection. Verify compatibility with other additives in your formulation before use.