Plasticizers

Triethyl Citrate (TEC)

CAS 77-93-0 — Pharmaceutical & Food-Grade Plasticizer

TEC is the primary plasticizer for pharmaceutical tablet coatings and controlled-release formulations, and is approved for food contact applications. Texas-Chem supplies pharmaceutical and food-grade TEC in bulk drums and totes.

CAS Number

77-93-0

Flash Point

Above 150 °C

Pharma Grade

EP/USP Compliant

Pack Sizes

Drums · Totes

Structure

C₁₂H₂₀O₇ — Triethyl Citrate (Pharma/Food Grade)Non-PhthalateEster PlasticizerCAS 77-93-0 | Non-flammable

C₁₂H₂₀O₇ — Triethyl Citrate — CAS 77-93-0

Safety & Regulatory

NFPA Health
1 — Slight hazard
NFPA Flammability
1 — Slight hazard
NFPA Reactivity
0 — Stable
Flash Point
Above 150 °C — Combustible
OSHA PEL
Not established
DOT Hazard Class
Not regulated

Grades & Packaging

Available Grades

Pharmaceutical Grade (EP/USP)Food Grade (FDA/EU)

Pack Sizes

55-gal Drums275-gal Totes

Also Known As

Triethyl CitrateTECCitric Acid Triethyl EsterEthyl Citrate

Physical & Chemical Properties

CAS Number77-93-0
Molecular FormulaC₁₂H₂₀O₇
Molecular Weight276.3 g/mol
AppearanceClear colorless liquid
Boiling Point294 °C
Flash PointAbove 150 °C — Combustible
Density1.135 g/cm³ at 20 °C
Vapor PressureLess than 0.01 mmHg at 20 °C
Viscosity~35 cP at 20 °C
Water Solubility6.5 g/100 mL at 20 °C
Food ContactFDA 21 CFR / EU Reg 10/2011 approved
Pharma GradeEP/USP compliant

Industrial Applications

Pharmaceutical Tablet Coatings

TEC is the most widely used plasticizer in pharmaceutical tablet coatings and controlled-release formulations, providing flexibility to HPMC, ethylcellulose, and Eudragit film coatings.

Controlled-Release Formulations

Used as a plasticizer in ethylcellulose and Eudragit RS/RL controlled-release coatings for oral solid dosage forms.

Food Contact Applications

TEC is approved for food contact and is used as a plasticizer in food packaging films, food service products, and direct food contact applications.

Personal Care

Used as a plasticizer in nail polish, hair spray, and other personal care formulations where a low-molecular-weight, water-compatible plasticizer is needed.

Medical Device Coatings

Used as a biocompatible plasticizer in medical device coatings and drug delivery systems.

Biodegradable Polymers

Used as a plasticizer in PLA and other biodegradable polymer formulations for sustainable packaging applications.

Why Source TEC from Texas-Chem

  • Pharmaceutical and food-grade TEC in stock — drums and totes
  • Consistent quality with CoA on every lot
  • Same-week delivery across Texas; nationwide LTL
  • Technical support for pharmaceutical coating and food contact applications
  • One rep from first call to final delivery
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Triethyl Citrate — Frequently Asked Questions

Is TEC approved for pharmaceutical tablet coatings?▾

Yes. TEC is listed in the FDA Inactive Ingredients Database for oral solid dosage forms and is compliant with the European Pharmacopoeia (EP) and USP. It is used as a plasticizer in HPMC, ethylcellulose, and Eudragit film coatings for immediate-release and controlled-release tablet formulations.

What is the typical use level of TEC in pharmaceutical coatings?▾

TEC is typically used at 10–30% by weight relative to the polymer in pharmaceutical film coatings. For ethylcellulose coatings (Surelease, Aquacoat ECD), 20–30% TEC relative to polymer is typical. For HPMC immediate-release coatings, 10–20% TEC is typical. Contact Texas-Chem for pharmaceutical-grade TEC with EP/USP compliance documentation.

What is the difference between TEC and TBC for pharmaceutical applications?▾

TEC (triethyl citrate, MW 276 g/mol) has lower molecular weight and higher water solubility than TBC (tributyl citrate, MW 360 g/mol), making it more compatible with aqueous coating systems and providing better plasticization of hydrophilic polymers (HPMC, HPC). TBC is preferred for hydrophobic polymer coatings (ethylcellulose) and flexible PVC applications. TEC is the standard plasticizer for pharmaceutical tablet coatings.

Is TEC approved for food contact applications?▾

Yes. TEC is approved for food contact applications under FDA 21 CFR 175.300 and EU Regulation 10/2011. It is used in food packaging films, food service products, and direct food contact applications. Contact Texas-Chem for food-grade TEC with FDA/EU compliance documentation.